Catalytic chain transfer polymerization(CCTP) of methyl methacrylate(MMA) and γ-methacryloxypropyltrimethoxysilane(MPS) was performed using toluene as the solvent at 60℃ in the present of bis(boron difluorodimethylglyoximate) cobaltate(Ⅱ)(CoBF) as catalytic chain transfer agent and AIBN as the initiator.
以钴Ⅱ肟氟化硼络合物(CoBF)为催化剂,2,2′-偶氮二异丁腈(AIBN)为引发剂,实现了甲基丙烯酸甲酯(MMA)与γ-甲基丙烯酰氧基丙基三甲氧基硅烷(MPS)在60℃甲苯体系中的催化链转移聚合(catalytic chaintransfer polymerization,CCTP),制备出末端含有双键的共聚物。
Block Copolymers by Transformation of Living Cationic Polymerization into Radical Polymerization;
活性正离子聚合/自由基聚合转化法合成嵌段共聚物的研究
Study on Conversion Rate of VAc-EA-St Emulsion Copolymerization
VAc-EA-St三元乳液共聚合转化率研究
Effects on the Conversion Ratio of Cationic Styrene-Acrylate Emulsion Polymerization
阳离子型苯丙乳液聚合转化率的影响因素
Progress in preparation of hyperbranched polymers via atom transfer radical polymerization
原子转移自由基聚合制备超支化聚合物进展
Conversion of butadiene solution polymerization by nickel catalyst system
镍催化体系丁二烯溶液聚合的转化率
The Application of Three-Stage Polymerization Model in Free Radical Copolymerization of High Conversion;
三段聚合模型在高转化自由基共聚中的应用
Preparation of Block Copolymer by Iodine Degenerative Transfer Radical Polymerization
碘原子退化转移自由基聚合制备嵌段共聚物
The Study on the Phase Separation and Gelation Transition in Physically Associating Polymer Solution;
物理缔合聚合物相分离及凝胶化转变的研究
Chain Transfer Reaction between Metal Complexes in Olefin Polymerization
烯烃聚合中金属化合物间的链转移反应
Atom Transfer Radical Polymerization Catalyzed by Immobilized Cobalt Catalyst;
负载钴催化剂催化原子转移自由基聚合研究
Glass transition temperature of polymers in supercritical carbon dioxide
超临界二氧化碳介质中聚合物玻璃化转变温度
Syntheses of Branched Polystrene by Self-condensing Atom Transfer Radical Copolymerization;
自缩合原子转移自由基共聚合制备支化聚苯乙烯
Photochemistry synthesis of PEI for gene delivery with high transfection efficiency
光化学法合成高基因转染效率的聚乙烯亚胺
Preparation of Gradient Ceramic/polymer Composites by Pyrolysis-impregination (PIP) Technique;
先驱体转化法制备无机基/有机聚合物梯度材料
Processing and Characterization of Polysiloxane Derived Ceramic Matrix Composites;
聚硅氧烷先驱体转化制备陶瓷基复合材料研究
Novel Catalyst Systems for Atom Transfer Radical Polymerizations;
原子转移自由基聚合新催化体系的研究
Study of Atom Transfer Radical Polymerization Mediated by Ferrous-based Catalyst;
铁系催化剂用于原子转移自由基聚合的研究
Path Transformation in Agricultural Industrialization: Industrial Convergence and Industrial Clustering;
农业产业化的路径转换:产业融合与产业集聚
